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Record W4224923198 · doi:10.3389/fmars.2022.845536

Using Radiocarbon Measurements of Dissolved Inorganic Carbon to Determine a Revised Residence Time for Deep Baffin Bay

2022· article· en· W4224923198 on OpenAlexafffundabout
Sara Zeidan, Jennifer Walker, Brent Else, Lisa A. Miller, Kumiko Azetsu‐Scott, Brett D. Walker

Bibliographic record

VenueFrontiers in Marine Science · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicMethane Hydrates and Related Phenomena
Canadian institutionsBedford Institute of OceanographyFisheries and Oceans CanadaUniversity of CalgaryUniversity of Ottawa
FundersDivision of Ocean SciencesFisheries and Oceans CanadaUniversity of California, IrvineNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsArcticNetUniversity of Ottawa
KeywordsBayOceanographyRadiocarbon datingArcticAlkalinityDissolved organic carbonGeologyTotal inorganic carbonEnvironmental scienceCarbon dioxideChemistryPaleontology

Abstract

fetched live from OpenAlex

The Canadian Arctic is warming at three times the rate of the rest of the planet and the effects of climate change on the Arctic marine carbon cycle remains unconstrained. Baffin Bay is a semi-enclosed, Arctic basin that connects the Arctic Ocean to the north to the Labrador Sea to the south. While the physical oceanography of surface Baffin Bay is well characterized, less is known about deep water formation mechanisms within the Basin. Only a few residence-time estimates for Baffin Bay Deep Water (BBDW) exist and range from 20 to 1450 years. Better residence time estimates are needed to understand the oceanographic significance of Baffin Bay. Here we report stable carbon (δ 13 C) and radiocarbon (Δ 14 C) values of dissolved inorganic carbon (DIC) collected aboard the CCGS Amundsen in 2019. DIC δ 13 C and Δ 14 C values between ranged between -0.7‰ to +1.9‰ and -90.0‰ to +29.8‰, respectively. Surface DIC δ 13 C values were between +0.7‰ to +1.9‰, while deep (>100m) values were 0.0 to -0.7‰. Surface DIC Δ 14 C values ranged between -5.4‰ to +22.9‰, while deep DIC (>1400m) DIC Δ 14 C averaged -82.2 ± 8.5‰ ( n = 9). To constrain natural DIC Δ 14 C values, we quantified the amount of atmospheric “bomb” 14 C in DIC (Δ 14 C bomb ; using the potential alkalinity method; P alk ) and anthropogenic DIC (DIC anth ; using the ΔC * method). Both proxies indicate an absence of Δ 14 C bomb and DIC anth below 1000m. Using two previously proposed deep water formation mechanisms and our corrected DIC Δ 14 C natural values, we estimated a 14 C-based residence time of 360-690 years for BBDW. Based on these residence times, we infer carbon is likely stored for centuries in deep Baffin Bay.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.687
Threshold uncertainty score0.675

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.239
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2022
Admission routes3
Has abstractyes

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