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Record W4225117907 · doi:10.11159/iceptp22.176

Steam Distillation of Acidulated Soapstock and FAME Synthesis

2022· article· en· W4225117907 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueProceedings of the World Congress on Civil, Structural, and Environmental Engineering · 2022
Typearticle
Languageen
FieldEngineering
TopicProcess Optimization and Integration
Canadian institutionsnot available
FundersEuropean Regional Development Fund
KeywordsDistillationProcess engineeringSteam distillationComputer scienceEnvironmental sciencePulp and paper industryChemistryEngineeringChromatography

Abstract

fetched live from OpenAlex

Use of rapeseed soapstock to produce biodiesel is a sustainable choice, because it deals with waste stream use in biofuel synthesis and lowers the use of food grade oil as fuel feedstock. Rapeseed soapstock was acidulated, and fatty acid and glycerides containing acid oil was separated from water phase. Steam distillation -a mild purification method -was used to separate fatty acids from acid oil. Distilled fatty acids were subjected to sulfuric acid catalyzed esterification with methanol. The chosen reaction conditions were: 65 C temperature, molar ratio of MeOH to FFA 20:1, 7.5 mol% H2SO4, and a reaction time 1 h. Esterification of distilled fatty acids proceeded with 98.3-98.5% conversion to FAME and product yield 93-95% from theoretical. The esterification reaction conditions were determined using lauric acid as model compound, the catalyst concentration was adjusted to be less than usually reported, so to avoid oxidation and side reactions. Use of ultrasound assisted synthesis was elaborated by comparing reaction of lauric acid at 25 C temperature in ultrasonic bath and with stirring. Reaction was faster with stirring than use of ultrasound.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.074
Threshold uncertainty score0.515

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.161
Teacher spread0.158 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it