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Record W4226216969 · doi:10.3390/nitrogen3020012

Degradation of N-(n-butyl) Thiophosphoric Triamide (NBPT) with and without Nitrification Inhibitor in Soils

2022· article· en· W4226216969 on OpenAlexaff
Ahmed A. Lasisi, O. O. Akinremi

Bibliographic record

VenueNitrogen · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicPesticide and Herbicide Environmental Studies
Canadian institutionsUniversity of Manitoba
Fundersnot available
KeywordsChemistrySoil waterNitrificationEnvironmental chemistryAmendmentDegradation (telecommunications)Soil pHAmmonia volatilization from ureaNuclear chemistryVolatilisationIncubationReaction rate constantUreaNitrogenKineticsSoil scienceOrganic chemistryBiochemistryGeology

Abstract

fetched live from OpenAlex

Recent studies have shown that nitrification inhibitor (NI) impairs the efficacy of urease inhibitor, N-(n-butyl) thiophosphoric triamide (NBPT), in reducing ammonia volatilization and urea hydrolysis rate. A laboratory study was conducted to evaluate the influence of NI (specifically 3,4-dimethyl pyrazole phosphate) on the degradation of NBPT in six soils. Soils were amended with either NBPT (10 mg NBPT kg−1 soil) or NBPT plus NI (DI; 10 mg NBPT + 2.5 mg NI kg−1 soil), incubated at 21 °C, and destructively sampled eight times during a 14-day incubation period. The degradation of NBPT in soil was quantified by measuring NBPT concentration with high-performance liquid chromatography-mass spectrometry, and the degradation rate constant was modeled with an exponential decay function. The study showed that the persistence of NBPT in soil was not influenced by the presence of NI, as the NBPT degradation rate constant across soils was 0.5 d−1 with either NBPT or DI. In contrast, the degradation rate constant was significantly dependent on soils, with values ranging from 0.4 to 1.7 d−1. Soil pH was the most important variable affecting the persistence of NBPT in soils. The half-life of NBPT was 0.4 d in acidic soil and 1.3 to 2.1 d in neutral to alkaline soils. The faster degradation of NBPT in acidic soils may explain its reduced efficacy in such soils.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.209
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2022
Admission routes1
Has abstractyes

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