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Record W4229056645 · doi:10.1021/acs.jnatprod.1c01225

Ansellone J, a Potent <i>in Vitro</i> and <i>ex Vivo</i> HIV-1 Latency Reversal Agent Isolated from a <i>Phorbas</i> sp. Marine Sponge

2022· review· en· W4229056645 on OpenAlexafffund
Meng Wang, Amanda Sciorillo, Silven Read, Donya Naz Divsalar, Kwasi Gyampoh, Guorui Zu, Zhe Yuan, Karam Mounzer, David E. Williams, Luis J. Montaner, Nicole J. de Voogd, Ian Tietjen, Raymond J. Andersen

Bibliographic record

VenueJournal of Natural Products · 2022
Typereview
Languageen
FieldMedicine
TopicHIV/AIDS drug development and treatment
Canadian institutionsSimon Fraser UniversityUniversity of British Columbia
FundersNational Institute of Allergy and Infectious DiseasesWellcomePhiladelphia FoundationCanadian Institutes of Health ResearchNew Partnership for Africa's DevelopmentSimon Fraser UniversityGovernment of the United KingdomNatural Sciences and Engineering Research Council of CanadaAfrican Academy of SciencesGovernment of CanadaWistar InstituteWellcome Trust
KeywordsEx vivoSpongeLatency (audio)In vitroIn vivoContext (archaeology)ChemistryStereochemistryHuman immunodeficiency virus (HIV)Activator (genetics)BiologyBiochemistryVirologyGeneticsBotany

Abstract

fetched live from OpenAlex

Five new minor sesterterpenoids, ansellones H ( 4 ), I ( 5 ), J ( 6 ), and K ( 7 ) and phorone C ( 8 ), have been isolated from a Phorbas sp. marine sponge collected in British Columbia. Their structures have been elucidated by detailed analysis of NMR and MS data. Ansellone J ( 6 ) and phorone C ( 8 ) are potent in vitro HIV-1 latency reversal agents that are more potent than the reference compound and control protein kinase C activator prostratin ( 3 ). The most potent Phorbas sesterterpenoid, ansellone J ( 6 ), was evaluated for HIV latency reversal in a primary cell context using CD4+ T cells obtained directly from four combination antiretroviral therapy-suppressed donors with HIV. To a first approximation, ansellone J ( 6 ) induced HIV latency reversal at levels similar to prostratin ( 3 ) ex vivo, but at a 10-fold lower concentration.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.003
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.264
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2022
Admission routes2
Has abstractyes

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Same venueJournal of Natural ProductsSame topicHIV/AIDS drug development and treatmentFrench-language works237,207