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Record W4229625143 · doi:10.1002/ange.200701194

The Geometric and Electronic Structure of a One‐Electron‐Oxidized Nickel(II) Bis(salicylidene)diamine Complex

2007· article· en· W4229625143 on OpenAlexfundno aff
Tim Storr, Erik C. Wasinger, Russell C. Pratt, T. Daniel P. Stack

Bibliographic record

VenueAngewandte Chemie · 2007
Typearticle
Languageen
FieldChemistry
TopicMetal-Catalyzed Oxygenation Mechanisms
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaNational Institutes of HealthU.S. Department of Energy
KeywordsChemistryDiamineNickelPolymer chemistryStereochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Klasse-III-Delokalisierung? Änderungen der Bindungssituation und das Ausmaß an Delokalisierung im Titelkomplex, der einen radikalischen Liganden trägt, wurden durch dessen Isolierung und Charakterisierung beschreibbar. Die intensive niederenergetische Absorption des oxidierten Komplexes kann als Übergang im radikalischen Liganden einer hochdelokalisierten gemischtvalenten Klasse-III-Verbindung interpretiert werden.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.253
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations42
Published2007
Admission routes1
Has abstractyes

Explore more

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