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Record W4239256070 · doi:10.1107/s2053273314097708

Twisted crystals

2014· article· en· W4239256070 on OpenAlexfundno aff
Alexander G. Shtukenberg, Bart Kahr

Bibliographic record

VenueActa Crystallographica Section A Foundations and Advances · 2014
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsnot available
FundersYork UniversityNational Science Foundation
KeywordsMaterials scienceCrystal (programming language)CrystallizationCrystallographyCrystal growthNucleationChemical physicsWhiskersComposite materialChemistry

Abstract

fetched live from OpenAlex

Modern reviews on crystal growth and defects in crystals overlook the fact that a significant portion of materials can spontaneously grow as single crystals with twisted and bent morphologies and curved crystal lattices. Twisted crystals can be found among all types of materials (molecular crystals, salts, minerals, high polymers, metals, and elements) crystallizing in any point and space group from all types of growth media (vapor, solution, gel, glass, melt, and solid state). Their size spans over more than six orders of magnitude ranging from nm where 3D character is equivocal, to cm or dm (some of the biggest natural crystals). Here are illustrated most important features of twisted crystals as well as an analysis of mechanisms that are responsible for this mysterious phenomenon [1]. In general, formation of a twisted crystal is a complex phenomenon involving with certain requirements for dissymmetry, isomorphism, and crystal chemistry. Also critical are processes at the crystal-medium interface as well as the elasticity and plasticity of the crystalline medium. As such, twisting is strongly controlled by morphology and symmetry of the growth face. It frequently requires impurities, sometimes in extremely low concentrations. The intensity of deformation is inversely proportional to the crystal size. The phenomenon is more common when the driving force for crystallization and the temperature are high. Several mechanisms have been proposed to explain the formation of unusual curved morphologies: axial dislocation in whiskers (Eshelby twist); surface stress in polymer lamellae; surface charge and spontaneous polarization in nanoribbons; inhomogeneous fields forming around a growing crystal; and internal stress created by an inhomogeneous impurity distribution. However, most of the mechanisms proposed are insufficiently developed and need further verification and elaboration. The work was supported by the US National Science Foundation and New York University.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.992
Threshold uncertainty score0.597

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.256
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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