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Record W4240099903 · doi:10.1002/ange.201607581

In Situ Generated Janus Fabrics for the Rapid and Efficient Separation of Oil from Oil‐in‐Water Emulsions

2016· article· en· W4240099903 on OpenAlexafffund
Zijie Wang, Guojun Liu, Shuaishuai Huang

Bibliographic record

VenueAngewandte Chemie · 2016
Typearticle
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsJanusEmulsionMethacrylateMaterials scienceSiloxaneSide chainContact angleChemical engineeringPolymerPolymer chemistryCoatingIn situPolymer scienceChemistryComposite materialNanotechnologyCopolymerOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract A cotton fabric was coated with a polymer that contains both poly(dimethyl siloxane) (PDMS) and poly( N , N ‐dimethylaminoethyl methacrylate) (PDMAEMA). When the repeat unit number of PDMS is about three‐fold that of PDMAEMA and the fabric is exposed to air, the fabric is superhydrophobic because PDMS in the coating covers the PDMAEMA chains. Upon contact with an oil‐in‐water emulsion, the water‐soluble PDMAEMA rises to the top and the side in contact with the emulsion becomes hydrophilic. The emerged PDMAEMA chains then cause the emulsion droplets to coagulate, and the aggregated oil fills the pores on the superhydrophobic side of the fabric. The oil‐impregnated side remains hydrophobic even upon prolonged contact with water. Thus, a Janus fabric is elegantly generated in situ and sustained. This easy‐to‐prepare Janus fabric rapidly and efficiently separates oil from emulsions and may find practical applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.253

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.027
GPT teacher head0.265
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations19
Published2016
Admission routes2
Has abstractyes

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