Bibliographic record
Abstract
[10377-51-2] ILi (MW 133.84) InChI = 1S/HI.Li/h1H;/q;+1/p-1 InChIKey = HSZCZNFXUDYRKD-UHFFFAOYSA-M (ester cleavage and decarboxylation;2 source of nucleophilic iodide;3 mild Lewis acid;1 salt effects in organometallic reactions;1 epoxide opening4) Physical Data: mp 449 °C; bp 1180 °C; d 4.076 g cm−3. Solubility: 165 g/100 mL H2O (20 °C); 433 g/100 mL H2O (80 °C); 251 g/100 mL EtOH (20 °C); 343 g/100 mL MeOH (20 °C); 43 g/100 mL acetone (18 °C); very sol NH4OH. Form Supplied in: anhydrous white solid or as the hydrate. Preparative Method: the anhydrous salt of high purity can be prepared from lithium hydride and iodine in ether.5 Purification: crystallized from hot H2O (0.5 mL g−1) by cooling in CaCl2–ice or from acetone. LiI is dried for 2 h at 120 °C (0.1 mmHg, P2O5) before use. Handling, Storage, and Precautions: for best results, LiI should be dried prior to use in anhydrous reactions.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.002 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.002 | 0.002 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.003 | 0.002 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.195 | 0.192 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".