MétaCan
Menu
Back to cohort
Record W4249864433 · doi:10.1055/s-0037-1612173

SYNFORM ISSUE 2019/06

2019· article· en· W4249864433 on OpenAlexaboutno aff
Matteo Zanda

Bibliographic record

VenueSynfacts · 2019
Typearticle
Languageen
FieldPharmacology, Toxicology and Pharmaceutics
TopicOrganoselenium and organotellurium chemistry
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryEarth scienceGeology

Abstract

fetched live from OpenAlex

June marks the beginning of summer, which is synonymous with holidays, but SYNfOrM has no inten tion whatsoever of going on holiday and if there was any doubt it is worth having a look at this new very thick issue, featuring four vibrant Literature Coverage articles. The first is an impressive study authored by a consortium of world-leading authors, led by B. L. Pentelute (USA), showing that complex and bioactive small molecules can be readily and late-stage functionalized with polypeptides and proteins via selenium-containing linkages, providing a variety of bioconjugates, including antibody-drug conjugates. In the second article, P. Melchiorre (Spain) goes through his group's recent work on the photochemical generation of a wide range of alkyl radicals, mediated by an N-indole-dithiocarbamate anion, and their manifold reactivity with heteroaromatics and Michael acceptors. The third contribution covers the development of a method for chiroptical screening and monitoring of asymmetric reactions based on a halocoumarin chromo phoric sensor, as a useful alternative to the mainstream NMr and HPLC methods for discriminating between enantiomers, as described by C. Wolf (USA), the leading author of this study. finally, in the last article of this issue, J. Scaiano (Canada) introduces the concept of 'catalytic farming' as a novel concept for improving the overall performance of homogeneous catalysts. I might just get on with booking my holidays now Enjoy your reading!!

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.306
Threshold uncertainty score0.987

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0350.048

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.378
Teacher spread0.342 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2019
Admission routes1
Has abstractyes

Explore more

Same venueSynfactsSame topicOrganoselenium and organotellurium chemistryFrench-language works237,207