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Record W4250568878 · doi:10.1149/ma2015-02/36/1272

Study of the Effect of Calcination Temperature on the Morphology and Activity of Iridium Oxide Electrocatalyst Supported on Antimony Tin Oxide (ATO) for PEM Electrolyser Technology

2015· article· en· W4250568878 on OpenAlexaff
Fatemeh Karimi, Brant A. Peppley, Aimy Bazylak

Bibliographic record

VenueECS Meeting Abstracts · 2015
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversity of TorontoQueen's University
Fundersnot available
KeywordsElectrocatalystTin oxideCalcinationMaterials scienceCyclic voltammetryThermogravimetric analysisChemical engineeringOxideInorganic chemistryCatalysisElectrochemistryChemistryElectrodeOrganic chemistryMetallurgyPhysical chemistry

Abstract

fetched live from OpenAlex

Iridium oxide nanoparticles supported on Antimony Tin oxide (ATO) have been used for oxygen evolution reaction in polymer electrolyte membrane (PEM) electrolysis. The morphology, crystallinity, catalyst-support interaction and electrocatalyst oxygen evolution reaction (OER) activity of the catalyst Iridium oxide supported on ATO at various calcination temperatures have been studied. The supported catalyst was synthesized using the modified Polyol method. The synthesized electrocatalyst was physically characterized by Differential Scanning Calorimetry, Thermogravimetric Analysis, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Brunauer, Emmett and Teller BET surface area measurements. The catalyst was electrochemically characterized by cyclic voltammetry and polarization measurements in a typical three electrode system. The main focus of this work is to study the effect of calcination temperatures of 200, 350, 500 and 700 ⁰C. Iridium oxide phases formed as a function of temperature, degree of crystallization as well as the interaction of Iridium oxide nanoparticles with the ATO nanoparticles support will be presented.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.000
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.229
Teacher spread0.220 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2015
Admission routes1
Has abstractyes

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Same venueECS Meeting Abstracts→Same topicFuel Cells and Related Materials→French-language works237,207→