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Record W4283025564 · doi:10.1002/cnma.202200154

TiO<sub>2</sub> Hollow Nanofiber/Polyaniline Nanocomposites for Ammonia Detection at Room Temperature

2022· article· en· W4283025564 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueChemNanoMat · 2022
Typearticle
Languageen
FieldEngineering
TopicGas Sensing Nanomaterials and Sensors
Canadian institutionsUniversity of Waterloo
FundersSistema de Laboratórios em Nanotecnologias, Universidade Federal de ViçosaConselho Nacional de Desenvolvimento Científico e TecnológicoMinistério da Ciência, Tecnologia e InovaçãoFundação de Amparo à Pesquisa do Estado de São Paulo
KeywordsNanocompositeMaterials scienceNanofiberPolyanilineElectrospinningCalcinationAnataseAmmoniaNanotechnologyPolyaniline nanofibersChemical engineeringHeterojunctionElectrodeNanostructureComposite materialPolymerOptoelectronicsPhotocatalysisChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Ammonia (NH 3 ) detection has gained considerable attention in agricultural and environmental monitoring, chemical and pharmaceutical processing, and disease diagnosis, which requires the development of sensors with high sensitivity. Herein, we propose a novel gas sensor based on nanocomposites of TiO 2 hollow nanofibers and polyaniline (PANI) for the sensitive detection of ammonia at room temperature. TiO 2 nanostructures in anatase phase were prepared by the combination of coaxial electrospinning and calcination treatment. The resulting material was mixed with PANI and deposited onto gold interdigitated electrodes (IDEs). The hybrid platforms exhibited superior sensing performance compared to the platform based on their individual phases, which is ascribed to a synergistic effect from p‐n heterojunction formation. Specifically, the platforms based on TiO 2 /PANI nanocomposite showed a fast response towards NH 3 (e. g., 55 s at 10 ppm) at room temperature (25 °C). Additionally, the platform demonstrated the ability to detect NH 3 at low concentrations (10–30 ppm) and a detection mechanism was proposed to explain the results. Overall, these results show the promise of electrospun TiO 2 hollow nanofibers/PANI composites for the development of high‐performance room temperature ammonia sensors.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.172
Teacher spread0.167 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it