An Aluminum‐Benzo[1,2‐b:4,5‐b’]dithiophene‐4,8‐dione Organic Rechargeable Battery Featuring Low Self‐Discharge
Bibliographic record
Abstract
Abstract The achievable cell‐level specific energy density of existing aluminum‐ion batteries (AIBs) employing AlCl4− intercalation type cathodes is intrinsically limited by the chloroaluminate anolyte. Towards achieving AIBs with higher specific energy, it is imperative to explore alternative cell chemistries that fundamentally tap the capacity of Al metal anode. Here, we report a benzo[1,2‐b:4,5‐b’]dithiophene‐4,8‐dione (BDTD) organic electrode material with favorable AlCl2+ intercalation mechanism. This BDTD cathode delivers a specific capacity of 143 mAh g−1, and the resulting battery exhibits a well‐defined voltage plateau at ∼1.2 V. This characteristic voltage plateau is mainly driven by the predominant diffusive charge storage in BDTD cathode, which accounts for up to 85 % of the total charge‐storage contribution. As a result, the BDTD cathode demonstrates exceptional self‐discharging resistance by recovering >95 % of its capacity upon 24‐h resting.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".