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Record W4294884473 · doi:10.1021/acs.iecr.2c01657

Effect of Porous Carbons’ Intrinsic Parameters on the Pressure Swing Adsorption of CO<sub>2</sub> from Biogas

2022· article· en· W4294884473 on OpenAlexaff
Sean M.W. Wilson, Sebastien Barrette

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2022
Typearticle
Languageen
FieldEngineering
TopicCarbon Dioxide Capture Technologies
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsBiogasAdsorptionPressure swing adsorptionAerogelChemical engineeringCarbon fibersPorosityMaterials scienceActivated carbonSpecific surface areaChemistryComposite materialOrganic chemistryWaste managementComposite numberCatalysis

Abstract

fetched live from OpenAlex

The current study investigates the use of six commercially available activated carbons and one carbon aerogel for the removal of CO 2 from biogas during biogas upgrading using pressure swing adsorption. Pure component CH 4 isotherms were determined gravimetrically at temperatures of 10, 30, 50, 70, and 90 °C and pressures up to 6.5 atm. This data was used to investigate the effect of intrinsic parameters of the carbons such as pore size, surface area, %oxidation, and ash content. In the high-pressure region, pore size in the range of <1 nm, <2 nm, and <3 nm significantly correlates to the CH 4 adsorption capacities. In the low-pressure region, the heterogeneous nature of the carbons dominates adsorption. Comparing CO 2 data to CH 4 data, carbons having a smaller pore size distribution, a higher %oxidation, and a higher %ash content are all beneficial for the separation of CO 2 from biogas. In this study, NZ-AC, M-30, and ACC have these favorable intrinsic properties along with large estimated working capacities, indicating them as prospective porous carbons for separating CO 2 from biogas.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.034
GPT teacher head0.262
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2022
Admission routes1
Has abstractyes

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