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Record W4296126377 · doi:10.1021/acs.estlett.2c00527

Quantitative Decomposition of Influencing Factors to Aerosol pH Variation over the Coasts of the South China Sea, East China Sea, and Bohai Sea

2022· article· en· W4296126377 on OpenAlexaff
Guochen Wang, Ye Tao, Jia Chen, Chengfeng Liu, Xiaofei Qin, Hao Li, Long Yun, Mingdi Zhang, Haitao Zheng, Huaqiao Gui, Jianguo Liu, Juntao Huo, Qingyan Fu, Congrui Deng, Kan Huang

Bibliographic record

VenueEnvironmental Science & Technology Letters · 2022
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsYork University
FundersMinistry of Science and Technology of the People's Republic of ChinaNational Natural Science Foundation of China
KeywordsAerosolDiel vertical migrationEnvironmental scienceChina seaAtmospheric sciencesDiurnal temperature variationSea breezeAmmoniumEnvironmental chemistryOceanographySeasonalityRelative humidityClimatologyChemistryMeteorologyGeologyEcologyGeographyBiology

Abstract

fetched live from OpenAlex

Aerosol acidity acts as a crucial parameter in regulating atmospheric chemistry; however, quantifying its major influencing factors is rare, especially at coastal regions which represent complex interfaces from both terrestrial and marine emissions and land breeze–sea breeze interactions. Three field campaigns conducted at coastal sites of the South China Sea, East China Sea, and Bohai Sea all revealed high aerosol acidity. By using a decomposition method based on the NH x phase-partitioning equilibrium, NH 3 and relative humidity (RH) were identified as the two most important driving factors to hourly aerosol pH variation. In addition, the contributions of driving factors to the diel aerosol pH variation were first revealed. RH and temperature tended to increase (decrease) the aerosol pH during nighttime (daytime), while NH 3 exhibited a reverse diurnal pattern. The diel cycles of aerosol liquid water and gas-particle partitioning of ammonium were responsible for the behavior of the driving factors of diel aerosol pH variation. Moreover, this study also highlighted that nonvolatile cations accounted for 8%–17% of the hourly aerosol pH variation, demonstrating that the role of sea salts in regulating coastal aerosol acidity cannot be ignored.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score0.026

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.191
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations22
Published2022
Admission routes1
Has abstractyes

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