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Record W4298032847

Combined analysis by GC (RI), GC-MS and 13C NMR of the supercritical fluid extract of Abies alba twigs

2010· article· en· W4298032847 on OpenAlexaff
E. Duquesnoy, B. Marongiu, A. Piras, Silvia Porcedda

Bibliographic record

VenueHAL (Le Centre pour la Communication Scientifique Directe) · 2010
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicBiological Activity of Diterpenoids and Biflavonoids
Canadian institutionsMinistère des Ressources naturelles et des Forêts (Québec)
Fundersnot available
KeywordsGas chromatography–mass spectrometrySupercritical fluidChemistryCarbon-13 NMRChromatographyAbies albaMass spectrometryOrganic chemistryBotanyPicea abiesBiology
DOInot available

Abstract

fetched live from OpenAlex

Two samples (leaves and twigs) of Abies alba Miller from Corsica were extracted using supercritical CO2 and their chemical
\ncompositions were compared with those of the essential oils obtained from the same batch of plant material. In total 45
\ncomponents were identified using combined analysis by GC (RI), GC-MS and 13C NMR. It was observed that the contents of
\nmonoterpenes (mainly represented by limonene, α-pinene and camphene) were significantly lower in the supercritical fluid
\nextract (SFE) than in the essential oil (EO). Conversely, the proportions of sesquiterpenes were much higher in CO2 extracts
\nthan in essential oils (around 30% vs 4%). Cis-abienol, a diterpene alcohol, was identified only in SFE, and the proportions of
\nthis constituent (7.5% and 17.3%) were determined using quantitative 13C NMR since it was under estimated using the standard
\nconditions of GC.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.031
Threshold uncertainty score0.384

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.213
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2010
Admission routes1
Has abstractyes

Explore more

Same venueHAL (Le Centre pour la Communication Scientifique Directe)Same topicBiological Activity of Diterpenoids and BiflavonoidsFrench-language works237,207