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Record W4313576251 · doi:10.1016/j.chemgeo.2023.121302

δ26Mg-δ13C-δ18O systems as geochemical tracers for dolomite recrystallization: A case study of lower Ordovician dolomite from Tarim Basin

2023· article· en· W4313576251 on OpenAlexaff
Hairuo Qing, Zhanfeng Qiao, Siyang Zhang, Jason Cosford, Anping Hu, Liang Feng, Yongsheng Wang, Jianfeng Zheng

Bibliographic record

VenueChemical Geology · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeology and Paleoclimatology Research
Canadian institutionsUniversity of Regina
FundersPetroChina Company Limited
KeywordsDolomiteDolomitizationGeologyRecrystallization (geology)δ18OGeochemistryOrdovicianMineralogyDiagenesisIsotopeStable isotope ratioPaleontologyStructural basinFacies

Abstract

fetched live from OpenAlex

Widespread replacement dolomite occurs commonly in the geologic record. These dolomites are generally characterized by different crystal sizes and shapes that have at times been interpreted to represent multistage dolomitization; although the variation of dolomite texture could also have resulted from the recrystallization of precursor dolomite. It is important, but challenging, to differentiate these two scenarios to better understand the nature of dolomite and the associated processes of dolomitization. Our study explores this problem by using δ26Mg, δ13C, and δ18O isotopes to characterize the different crystal morphologies exhibited by Ordovician dolomites from the Tarim Basin, China. Although the dolomites show distinct textures and crystal morphologies, there are no discernible trends in their δ26Mg values (from −1.66 to −2.39‰), suggesting that these dolomites were formed by the same dolomitizing fluid. This interpretation is supported by an overlapping range of δ13C values (from 0.46 to −1.89‰). By contrast, the δ18O data demonstrate a wide range of values, from −3.8‰ to −8.8‰, reflecting the different degree of recrystallization with increasing burial temperatures. We suggest that the Mg and C isotopes remained unchanged during recrystallization because Mg and C were rock-buffered, so the recrystallized dolomite inherited Mg and C from the precursor dolomite. Based on these results, it appears that Mg isotopes, together with conventional OC isotopes, can provide a diagenetically robust geochemical tracer for identifying dolomite recrystallization in the geological record.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.512
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.283
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2023
Admission routes1
Has abstractyes

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