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Record W4313596181 · doi:10.1002/eem2.12586

<scp>3D</scp> Grid of Carbon Tubes with <scp>Mn<sub>3</sub>O<sub>4</sub>‐NPs</scp>/<scp>CNTs</scp> Filled in their Inner Cavity as Ultrahigh‐Rate and Stable Lithium Anode

2023· article· en· W4313596181 on OpenAlexaff
Shiping Zhang, Fangming Han, Qijun Pan, Dou Lin, Xiaoguang Zhu, Cheng Shao, Gaixia Zhang, Zhaoming Wang, Shuhui Sun, Guowen Meng

Bibliographic record

VenueEnergy & environment materials · 2023
Typearticle
Languageen
FieldEngineering
TopicAdvancements in Battery Materials
Canadian institutionsInstitut National de la Recherche ScientifiqueÉcole de Technologie Supérieure
FundersHefei Institutes of Physical Science, Chinese Academy of SciencesChinese Academy of SciencesNational Natural Science Foundation of China
KeywordsMaterials scienceAnodeElectrochemistryLithium (medication)ElectrodeCarbon fibersNanoparticleCarbon nanotubeIntercalation (chemistry)NanotechnologyIonConductivityTransition metalVolume expansionChemical engineeringComposite numberComposite materialChemistryInorganic chemistryCatalysis

Abstract

fetched live from OpenAlex

Transition metal oxides are regarded as promising candidates of anode for next‐generation lithium‐ion batteries (LIBs) due to their ultrahigh theoretical capacity and low cost, but are restricted by their low conductivity and large volume expansion during Li + intercalation. Herein, we designed and constructed a structurally integrated 3D carbon tube (3D‐CT) grid film with Mn 3 O 4 nanoparticles (Mn 3 O 4 ‐NPs) and carbon nanotubes (CNTs) filled in the inner cavity of CTs (denoted as Mn 3 O 4 ‐NPs/CNTs@3D‐CT) as high‐performance free‐standing anode for LIBs. The Mn 3 O 4 ‐NPs/CNTs@3D‐CT grid with Mn 3 O 4 ‐NPs filled in the inner cavity of 3D‐CT not only afford sufficient space to overcome the damage caused by the volume expansion of Mn 3 O 4 ‐NPs during charge and discharge processes, but also achieves highly efficient channels for the fast transport of both electrons and Li + during cycling, thus offering outstanding electrochemical performance (865 mAh g −1 at 1 A g −1 after 300 cycles) and excellent rate capability (418 mAh g −1 at 4 A g −1 ) based on the total mass of electrode. The unique 3D‐CT framework structure would open up a new route to the highly stable, high‐capacity, and excellent cycle and high‐rate performance free‐standing electrodes for high‐performance Li‐ion storage.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.035
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.177
Teacher spread0.171 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations21
Published2023
Admission routes1
Has abstractyes

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