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Record W4323065392 · doi:10.1039/d3dt00224a

Spectroscopy, molecular structure, and electropolymerization of Ni(<scp>ii</scp>) and Cu(<scp>ii</scp>) complexes containing a thiophene-appending fluorinated Schiff base ligand

2023· article· en· W4323065392 on OpenAlexfundno aff
Guillermo Ahumada, Paul Hamon, Thierry Roisnel, Vincent Dorcet, Mauricio Fuentealba, Loreto A. Hernández, David Carrillo, Jean‐René Hamon, Carolina Manzur

Bibliographic record

VenueDalton Transactions · 2023
Typearticle
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsnot available
FundersInstitute of Circulatory and Respiratory HealthCentre National de la Recherche ScientifiqueComisión Nacional de Investigación Científica y TecnológicaFondo Nacional de Desarrollo Científico y TecnológicoUniversité de Rennes 1Pontificia Universidad Católica de ValparaísoKungliga Tekniska Högskolan
KeywordsThiopheneChemistrySchiff baseTrifluoromethylLigand (biochemistry)CrystallographyElectrochemistryStereochemistryPhysical chemistryOrganic chemistryElectrode

Abstract

fetched live from OpenAlex

Electropolymerization of the title compounds yields golden-colored deposits, with the Cu( ii ) monomer enabling the formation of thicker coatings with increased conductivity in both CV and chronoamperometry voltammetric profiles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.258
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2023
Admission routes1
Has abstractyes

Explore more

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