MétaCan
Menu
Back to cohort
Record W4323816852 · doi:10.1016/j.jobab.2023.03.003

Effect of silica source on photocatalytic properties of Bi2O3/Bi2SiO5 heterostructure

2023· article· en· W4323816852 on OpenAlexvenueno aff
Olga D. Arefieva, M. S. Vasilyeva, Л. А. Земнухова, D.P. Opra, D.A. Nikolaeva, В. В. Ткачев, Daria H. Shlyk

Bibliographic record

VenueJournal of Bioresources and Bioproducts · 2023
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsnot available
FundersRussian Science Foundation
KeywordsPhotocatalysisMaterials sciencePhotodegradationFourier transform infrared spectroscopyScanning electron microscopeMethyl orangeNuclear chemistryDiffuse reflectance infrared fourier transformHuskBiogenic silicaChemistryChemical engineeringComposite materialOrganic chemistryCatalysisBotany

Abstract

fetched live from OpenAlex

The Bi2O3/Bi2SiO5 heterostructures were obtained with various samples of silica as a precursor: on the basis of biogenic silica isolated from rice husk and rice straw and the silica of mineral origin. A mixture of Bi(NO3)3 and SiO2 with a mass content of 15% was used for synthesizing all the samples. Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscope (SEM), X-ray phase, X-ray fluorescence, and ultraviolet-visible diffused reflectance spectroscopy (UV-vis DRS) were used to systematically characterize as-obtained materials. Photodegradation of methyl orange in neutral aqueous solutions (pH = 6.8) under UV irradiation was studied to evaluate their photocatalytic activities. Morphology, bandgaps, the value of the zero charge point, and photocatalytic activity of the samples depended on the characteristics of the original silica. The degree of methyl orange degradation reached the maximum values (81%−85%) for samples based on precipitated silica from rice husks, straw, and the minimum value (16%) for a composite with thermal silica from rice straw. Composites based on thermal silica from rice husks and reagents from mineral raw materials did not statistically differ from each other in the degree of methyl orange degradation (67%−74%).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score0.632

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.245
Teacher spread0.234 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations14
Published2023
Admission routes1
Has abstractyes

Explore more

Same venueJournal of Bioresources and BioproductsSame topicAdvanced Photocatalysis TechniquesFrench-language works237,207