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Investigation of soot suppression by ammonia addition to laminar ethylene flames at varying pressure

2023· article· en· W4360884890 on OpenAlexafffund
Francisco Cepeda, Seth B. Dworkin, Ahmet E. Karataş

Bibliographic record

VenueCombustion and Flame · 2023
Typearticle
Languageen
FieldChemical Engineering
TopicAdvanced Combustion Engine Technologies
Canadian institutionsToronto Metropolitan University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsSootChemistryAmmoniaCombustionVolume (thermodynamics)HydrocarbonVolume fractionLaminar flowFraction (chemistry)Atmospheric pressureMole fractionCarbon fibersNOxEthyleneAnalytical Chemistry (journal)Chemical engineeringOrganic chemistryMaterials scienceThermodynamicsMeteorologyPhysical chemistry

Abstract

fetched live from OpenAlex

Blending ammonia with hydrocarbon fuels is a promising pathway to expedite its use in different industries, as it might offer a good compromise between energy output and minimizing the emissions of both NOx and carbonaceous combustion products , including soot. This work describes the effects of pressure on soot formation in ethylene/ammonia laminar co-flow diffusion flames . A high-pressure chamber was used to study the flames at pressures between 1 to 7 atm, and ammonia addition mole fractions between 0 and 50% (38% in mass fraction). Soot volume fraction and soot temperature measurements using a Spectral Soot Emissions technique show that adding a 50% mole fraction of ammonia at atmospheric pressure reduces soot concentration below the detection limit of the technique and between 70% and 80% for all the remaining studied pressures; that is, the ammonia soot suppression characteristics are demonstrated when increasing pressure. Maximum soot yield and total volumetrically integrated soot volume fraction results are investigated to reveal the contrasting effects of pressure and ammonia addition on the flame structure and the soot formation mechanisms. The results showcase the potential of NH 3 in high-pressure applications when mixed with hydrocarbon fuels to reduce carbon emissions .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.238
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2023
Admission routes2
Has abstractyes

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