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Record W4362559747 · doi:10.1002/cjce.24905

Regeneration of [Fe( <scp>II</scp> )‐ <scp>NTA</scp> ] <sup>−</sup> catalyzed by activated carbon in the simultaneous removal of sulphur dioxide and nitric oxide

2023· article· en· W4362559747 on OpenAlexvenueno aff
Xiang‐li Long, Li Gong, Cong Li

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2023
Typearticle
Languageen
FieldEngineering
TopicIndustrial Gas Emission Control
Canadian institutionsnot available
Fundersnot available
KeywordsCatalysisActivated carbonChemistrySpace velocitySulfurNuclear chemistryInorganic chemistryAdsorptionOrganic chemistrySelectivity

Abstract

fetched live from OpenAlex

Abstract The combined control of NO and SO 2 can be finished with the [Fe(II)‐NTA] − solution because [Fe(II)‐NTA] − is capable of binding NO. However, the ability of [Fe(II)‐NTA] − to bind NO may be lost quickly due to the fast oxidation of [Fe(II)‐NTA] − to [Fe(III)‐NTA] by oxygen in the flue gases. To make it possible to put this technology into commercial application, efficient measures should be taken to regenerate [Fe(II)‐NTA] − to maintain the NO removal efficiency for a long time. The catalytic activity of activated carbon in the reproduction of [Fe(II)‐NTA] − has been investigated in a fixed‐bed reactor. The experiments indicate that [Fe(II)‐NTA] − reproduction increases with [Fe(III)‐NTA] and SO 3 2− concentrations as well as temperature. Fast flow and high pH are unfavourable for the reproduction of [Fe(II)‐NTA] − . An NO removal efficiency of 80.11%–89.78% is sustained for a long period of time with the [Fe(II)‐NTA] − reproduction catalyzed by activated carbon. The reaction orders with respect to [Fe(III)‐NTA] and SO 3 2− are 0.784 and 0.336, respectively. The apparent activation energy for this catalytic reaction is estimated to be 41.01 kJ mol −1 .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.136
Threshold uncertainty score0.799

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.184
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2023
Admission routes1
Has abstractyes

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