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Record W4364380976 · doi:10.1002/cjce.24906

Design framework for dimethyl ether ( <scp>DME)</scp> production from coal and biomass‐derived syngas via simulation approach

2023· article· en· W4364380976 on OpenAlexvenueno aff
Komal Tripathi, Vrinda Gupta, Varsha Awasthi, Kamal Kishore Pant, Sreedevi Upadhyayula

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2023
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsnot available
FundersMinistry of Education, India
KeywordsSyngasDimethyl etherMethanolCoalFischer–Tropsch processYield (engineering)Biomass (ecology)ChemistryGibbs free energyChemical engineeringProcess engineeringPulp and paper industryWaste managementMaterials scienceOrganic chemistryCatalysisThermodynamicsSelectivityEngineering

Abstract

fetched live from OpenAlex

Abstract A comprehensive thermodynamic study was conducted to evaluate the comparative efficacy of methanol and dimethyl ether (DME) synthesis using CO 2 rich syngas feed. The first part of our study included assessing the relative performances of the methanol synthesis system, two step DME synthesis system, and one step DME synthesis system in terms of the CO x conversion and product yield (methanol/DME) based on the Gibbs free energy minimization approach. The wide range of composition of CO 2 ‐enriched syngas feed produced by the coal and biomass gasification was simulated using Aspen Plus and the following evaluation parameters were analyzed for a broad parameter range: reaction temperature (180–280°C), reaction pressure (10–80 bar), stoichiometry number (SN) (0–11), and CO 2 /(CO 2 + CO) molar feed ratio (0–1) for isothermal as well as adiabatic conditions. Based on the equilibrium yield, one‐step DME synthesis was discovered as the most viable process to utilize the co‐gasification derived syngas effectively. In the second part of our study, the overall process efficiency was inspected through the process design of 1 tonnes per day (TPD) DME plant inclusive of heat integration, resulting in significant CO 2 abatement and DME production with high product purity and minimum energy consumption. Consequently, one‐step DME production via CO 2 ‐enriched syngas obtained through the coal or biomass gasification process is identified as the leading technology based on energy utilization and CO 2 abatement.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.381
Threshold uncertainty score0.761

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.234
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2023
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical EngineeringSame topicCatalysts for Methane ReformingFrench-language works237,207