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Record W4365998692 · doi:10.1029/2023gb007715

Linking Dissolved Organic Matter to CO<sub>2</sub> and CH<sub>4</sub> Concentrations in Canadian and Chilean Peatland Pools

2023· article· en· W4365998692 on OpenAlexafffundabout
Mahmud Hassan, Julie Talbot, Julien Arsenault, Karla Martinez‐Cruz, Armando Sepulveda‐Jauregui, Jorge Hoyos‐Santillan, Jean‐François Lapierre

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicPeatlands and Wetlands Ecology
Canadian institutionsUniversité de Montréal
FundersFonds de recherche du Québec – Nature et technologiesNatural Sciences and Engineering Research Council of CanadaAgencia Nacional de Investigación y DesarrolloGroupe de recherche interuniversitaire en limnologie
KeywordsPeatDissolved organic carbonEnvironmental scienceNutrientPrimary productionEnvironmental chemistryOrganic matterEcosystemGreenhouse gasPrecipitationVegetation (pathology)Hydrology (agriculture)Physical geographyEcologyChemistryGeologyGeographyBiology

Abstract

fetched live from OpenAlex

Abstract Peatland open‐water pools can be net carbon (C) emitters within heterogeneous peatland ecosystems that are generally net C sinks. However, the intra‐ and inter‐regional patterns and drivers of CO 2 and CH 4 production, as well as their link with dissolved organic matter (DOM) quality and quantity, remain poorly understood. We analyzed a range of optical characteristics and chemical variables controlling DOM and CO 2 and CH 4 concentrations in peatland pools across two regions with contrasting geographical properties (i.e., climate, topography, morphometry, and vegetation cover) of eastern Canada and Chilean Patagonia. We found inter‐regional patterns in CO 2 , CH 4 and DOM concentrations and composition that were coherent with patterns in mean annual temperature and precipitation, and vegetation cover. Cross‐regional patterns of CO 2 and CH 4 were driven by morphometry, vegetation cover, and protein‐like DOM composition, a proxy of high biological activity, whereas temporal variations of CO 2 and CH 4 concentrations were further influenced by seasonal changes in humic‐like DOM composition, dissolved organic carbon and nutrients (i.e., total phosphorus and total nitrogen) concentrations, as well as pH and oxygen levels. Our results suggest that geophysical constraints associated with local peat and pool characteristics as well as climate patterns are major drivers of DOM and greenhouse gases concentrations and the links between them in broadly distributed peatland pools.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.249
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.219
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations31
Published2023
Admission routes3
Has abstractyes

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