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Record W4367050761 · doi:10.21203/rs.3.rs-2759604/v1

Effects of C-S-Hs-PCE and Na2SO4 on hydration behavior of cement-lithium slag binder

2023· preprint· en· W4367050761 on OpenAlexaff
Yan He, Juan Chen, Shuhua Liu, Mingjing Jiang, R.D. Hooton

Bibliographic record

VenueResearch Square · 2023
Typepreprint
Languageen
FieldEngineering
TopicConcrete and Cement Materials Research
Canadian institutionsUniversity of Toronto
FundersNational Natural Science Foundation of China
KeywordsSodium sulfateNucleationEttringiteSulfateCementChemistryDissolutionPortland cementChemical engineeringSodiumInorganic chemistryPozzolanic reactionGypsumNuclear chemistryMaterials sciencePozzolanMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Application of C-S-Hs-PCE and sodium sulfate into Portland cement containing 20 wt% lithium slag (LS) powder was investigated, in order to strengthen early mechanical properties. Synergistic effects of C-S-Hs-PCE and sodium sulfate on hydration properties and microstructure of cement-LS system were analyzed. Results showed that C-S-Hs-PCE was advantageous for modifying fluidity of fresh LS-cement binder, while increased dosage of sodium sulfate decreased dispersibility of fresh paste. C-S-Hs-PCE and sodium sulfate exhibited a synergistic effect on strength enhancement, hydration acceleration as well as setting behavior of LS-cement binder. Sodium sulfate increased alkalinity of interstitial solution and promoted dissolution of LS. Dissolved Al and Si from LS powder reacted with dissolved sulfate ions from sodium sulfate to produce extra hydrates, and C-S-Hs-PCE accelerated pozzolanic reaction as well as hydration reaction via nucleation effect collaborated with dispersing effect. C-S-Hs-PCE accelerated reaction process of sodium sulfate via nucleation effect, and activation effect of sodium sulfate provided more newly-formed hydrates to act as nucleation seeds or crystal skeleton for induce hydration of new phases. The accelerated hydration generated more AFt and C-S-H gel in the matrix. Newly formed hydrates promoted exceedingly the appearance of network, leading to a refinement of pore structure as well as enhancement in mechanical strength. Application of LS into cement as a greener binder could be obtained by synergistic adoption of C-S-Hs-PCE and sodium sulfate.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.060
GPT teacher head0.363
Teacher spread0.304 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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