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Record W4372311942 · doi:10.1016/j.jconhyd.2023.104200

Nitrate in shallow groundwater after more than four decades of manure application

2023· article· en· W4372311942 on OpenAlexafffund
Emily Kyte, Edwin E. Cey, Leila Hrapovic, Xiying Hao

Bibliographic record

VenueJournal of Contaminant Hydrology · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGroundwater and Isotope Geochemistry
Canadian institutionsAgriculture and Agri-Food CanadaBGC Engineering (Canada)University of Calgary
FundersAgriculture and Agri-Food CanadaNatural Sciences and Engineering Research Council of Canada
KeywordsGroundwaterManureNitrateEnvironmental scienceHydrology (agriculture)DenitrificationFertilizerSpatial distributionSpatial variabilityWater qualityIrrigationAquiferNitrogenAgronomyGeologyChemistryEcology

Abstract

fetched live from OpenAlex

Over-application of manure to agricultural fields can leach nitrogen below the root zone and contaminate groundwater. The goal of this study was to evaluate the factors affecting the spatial and temporal distribution of nitrate in shallow groundwater following 44 years of manure application to irrigated and non-irrigated long-term test plots. Sampling of 26 wells over an 18-month period revealed high spatial variability of groundwater nitrate concentrations, ranging from <0.1 mg-N/L to 1350 mg-N/L (mean = 118 mg-N/L). The highest concentrations were associated with the highest manure nitrogen loads, longer durations of manure application, and were generally located beneath irrigated land use. Regression modeling confirmed that cumulative manure loading had the greatest control on the spatial distribution of groundwater nitrate. A significant decreasing temporal trend was observed in selected wells downgradient of plots where manure application ceased more than a decade earlier. Isotopic analysis of 15N-NO3 and 18O-NO3 showed that denitrification occurred at 16 well locations, with evidence for dissolved organic carbon as the electron donor. The groundwater nitrate trends observed in this long-term study demonstrate that historical nutrient and water management practices will affect groundwater quality for many decades to come.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.330

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.218
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2023
Admission routes2
Has abstractyes

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