Geochronology and geochemistry of zircon from Early to Middle Devonian granitic and felsic volcanic rocks from the Cashes Ledge igneous suite, central Gulf of Maine, USA
Bibliographic record
Abstract
New zircon U–Pb, trace element, and Lu–Hf laser ablation inductively coupled mass spectrometry (LA-ICP-MS) data are presented for five Early to Middle Devonian granitic and felsic volcanic rocks from the Cashes Ledge igneous suite, central Gulf of Maine, USA. These samples were previously analyzed by U–Pb LA-ICP-MS and whole-rock geochemical methods and the new data generally corroborate the earlier results. Coarse-grained alkali-feldspar granite from northwest of the Fundy magnetic anomaly, the interpreted fault boundary in the offshore between Gondwanan microcontinents Ganderia to the northwest and Avalonia to the southeast, yielded a crystallization age of 414 ± 2 Ma. Southeast of the inferred fault, crystallization ages are 385 ± 3 Ma and 386 ± 3 Ma for two crystal tuff samples near the fault, 403 ± 3 Ma for an alkali-feldspar granite ~50 km southeast of the fault, and 399 ± 5 Ma for syenogranite ~25 km southeast of the fault, which also yielded inherited grains at ~1.3 Ga and between 613 ± 15 Ma and 558 ± 9 Ma. Lu–Hf LA-ICP-MS data for zircon retaining igneous crystallization ages have εHf(t) between 2.9 and 13.1 and model ages based on felsic sources between 0.52 and 1.04 Ga, reflecting a mix of late Mesoproterozoic (Avalonian?) basement and primitive melt, possibly in an extensional setting. Zircon Nb/Hf ratios generally greater than 0.001 indicate a predominately within-plate/anorogenic/rift setting, consistent with their whole-rock chemistry. U/Yb-Nb/Yb and U/Yb-Hf tectonic setting discrimination diagrams show ocean island to continental arc signatures, with a stronger continental arc signature for the syenogranite. Most zircon grains have Eu/Eu* values less than 0.1, indicating a crustal thickness of ~30 km or less at the time of their crystallization.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".