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Record W4383340710 · doi:10.21203/rs.3.rs-2992953/v1

Exploring persistent organic pollutants (POPs) in the Danube River: An analysis of Polybrominated diphenyl ethers (PBDEs) and Per- and Polyfluorinated Substances (PFAS) using NORMAN Database

2023· preprint· en· W4383340710 on OpenAlexaff
Priyam Saxena, Atanu Sarkar, Rashmi R. Hazarika, Abhishek Pattanaik, Om Prakash Yadav, Gopal Achari

Bibliographic record

VenueResearch Square · 2023
Typepreprint
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsUniversity of CalgaryMemorial University of Newfoundland
Fundersnot available
KeywordsPolybrominated diphenyl ethersBiotaPollutantEnvironmental scienceEnvironmental chemistrySedimentPollutionSurface waterEnvironmental engineeringChemistryEcologyGeology

Abstract

fetched live from OpenAlex

Abstract Polybrominated diphenyl ethers (PBDEs) and per- and polyfluoroalkyl substances (PFAS) are environmental contaminants that have been widely detected in various matrices, including air, water, sediment, and biota, across the globe, but their sources and fate remain poorly understood. This review aims to explore the occurrence of PBDEs and PFAS in the Danube River. The study employs the NORMAN database repository as a source of data pertaining to persistent organic pollutants (POPs). This study compares and evaluates the occurrence patterns of PBDEs and PFAS in various countries along the Danube River basin. The spatial results demonstrate a decreasing trend for PBDEs in surface water and biota, while a significant increase for PFAS is observed. The distributions of PBDE congeners in biota samples mirrored the compositional profiles in the water, which were dominated by BDE-47 and/or BDE-99, while BDE-209 predominated in sediments. In regards to PFAS, PFOA and PFOS are prevalent in surface water. In conclusion, the occurrence of PBDEs and PFAS in Europe is of significant concern, and regulatory policies have been implemented to control their use and release into the environment. The results of this study can be used to assess the health and environmental risks posed by POPs in the Black Sea and can aid in the formulation of future public health policies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score0.056

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0030.004
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.215
GPT teacher head0.379
Teacher spread0.164 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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