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Record W4383557220 · doi:10.1002/pen.26427

Simultaneous crosslinking and foaming of ethylene‐propylene diene terpolymers (<scp>EPDM</scp>) organoclay composite foams

2023· article· en· W4383557220 on OpenAlexafffund
Arvind Gupta, Mehdi Jonoobi, Tizazu H. Mekonnen

Bibliographic record

VenuePolymer Engineering and Science · 2023
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Foaming and Composites
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceComposite materialComposite numberFourier transform infrared spectroscopyElastomerBlowing agentCompoundingOrganoclayThermal stabilityCompression moldingPolymerThermal decompositionNatural rubberEthylene propylene rubberUltimate tensile strengthWood-plastic compositeCopolymerChemical engineeringPolyurethaneOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract This study used ethylene‐propylene diene monomers (EPDM), an elastomer, to develop foams incorporating clay as filler using simple compounding, chemical foaming, and peroxide‐mediated light crosslinking methods. The low‐temperature batch mixer was employed for compounding azodicarbonamide (ADC) as a foaming agent, dicumyl peroxide (DCP) as a crosslinker, followed by compression molding for sheet preparation and the high‐temperature foaming process. Fourier transform infrared spectroscopy (FTIR) equipped with a hot stage attenuated total reflection (ATR) was employed to elucidate the ADC decomposition and foaming. The DCP (0.25 phr) content was optimized based on the foaming expansion ratio (>4) and stability, which was further optimized in conjuncture with clay to generate high‐performance composite foams. The incorporation of 1% organoclay enhances the expansion ratio and specific tensile strength by >7 and ~ 270%, respectively, compared with EPDM foams without clay while displaying a density of 0.11 g/cm3. Overall, the developed foaming process can be extended to other elastomeric polymers for various applications such as protective gears (e.g., helmets and shin guards), thermal/sound insulation, packaging/containment, footwear soles, oil absorption, etc.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.217
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2023
Admission routes2
Has abstractyes

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