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Record W4384156344 · doi:10.1016/j.chemgeo.2023.121630

Apatite laser ablation Lu Hf geochronology: A new tool to date mafic rocks

2023· article· en· W4384156344 on OpenAlexaboutno aff
Melissa Kharkongor, Stijn Glorie, Jacob A. Mulder, Christopher L. Kirkland, David Chew, Barry P. Kohn, Alexander Russell Simpson

Bibliographic record

VenueChemical Geology · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeological and Geochemical Analysis
Canadian institutionsnot available
FundersAustralian Research CouncilUniversity of Melbourne
KeywordsMaficGeologyGeochemistryIgneous rockGeochronologyApatiteArcheanZirconFelsicDharwar CratonCratonMetasomatismBaddeleyitePetrologyMantle (geology)Paleontology

Abstract

fetched live from OpenAlex

Mafic rocks are the most common type of igneous rocks on Earth, however, constraining the crystallization age of mafic rocks can be challenging. Apatite is a common accessory phase in mafic rocks and is amenable to dating using the UPb system. However, the UPb system in apatite has a relatively low closure temperature (~350°-550 °C) and is therefore prone to resetting by later thermal and metasomatic events. Here, a recently developed LuHf dating method using laser ablation reaction-cell mass spectrometry is applied to apatite from mafic rocks. The LuHf system in apatite has a higher closure temperature (~650°-750 °C) compared to UPb, increasing the chances of obtaining primary crystallization ages. Furthermore, the laser-ablation method allows rapid data collection compared to traditional solution-based LuHf dating techniques. Four study areas were selected to compare the LuHf vs UPb systematics of apatite in mafic igneous rocks: the Paleoproterozoic Sudbury Igneous Complex (Canada), the Neoproterozoic Borborema Province (NE Brazil), the Paleoproterozoic Fennoscandian Shield (Finland), the Archean Yilgarn Craton and Mesoproterozoic Albany Fraser-zone (Western Australia). For all analysed samples, where the apatite trace element composition records an undisturbed primary mafic igneous lithology, the LuHf system retains primary igneous apatite crystallization ages, whereas the UPb system in the same grains often records isotopic disturbance or a cooling age. In few cases, the LuHf system has also been disturbed in response to recrystallization, however, such disturbance is readily detected with trace element data. Hence, this study demonstrates the potential of laser ablation apatite LuHf dating to obtain primary crystallization ages for otherwise difficult to date mafic rocks.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.121
Threshold uncertainty score0.987

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0250.014

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.210
Teacher spread0.196 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations25
Published2023
Admission routes1
Has abstractyes

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