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Record W4384282614 · doi:10.1021/acs.est.2c09115

Cross-Species Evaluation of Bioaccumulation Thresholds for Air-Breathing Animals

2023· article· en· W4384282614 on OpenAlexafffund
L. Saunders, Frank Wania

Bibliographic record

VenueEnvironmental Science & Technology · 2023
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsThe Scarborough HospitalUniversity of Toronto
FundersUniversity of Toronto ScarboroughEuropean Chemical Industry Council
KeywordsBiomagnificationBioaccumulationEnvironmental chemistryExhalationRespirationHexachlorobenzeneEcologyChemistryBiologyPollutantBotanyAnatomy

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide In air-breathing organisms, an organic chemical’s susceptibility to elimination via urinary excretion and respiratory exhalation can be judged on the basis of the octanol–water partition ratio ( K OW ) and the octanol–air partition ratio ( K OA ), respectively. Current regulations specify that chemicals with K OW values of <10 2 and K OA values of <10 5 may be screened as non-bioaccumulative in air breathers. Here we used a model-based approach to evaluate whether these thresholds are consistent with a biomagnification factor of 1 for 141 different mammals, birds, and reptiles. Animals with lower rates of respiration (e.g., manatees and sloths) and those ingesting high-lipid diets (e.g., polar bears and carnivorous birds) were predicted to be able to biomagnify persistent chemicals with K OA values of <10 5 . This was also observed for several temperate reptiles due to their lower respiration rates and internal temperatures. Protective K OA thresholds were determined to be <10 4.85 for mammals, <10 4.60 for birds, <10 4.60 for reptiles at >25 °C, and <10 3.95 for reptiles at ≤25 °C. For all animals, urination alone was not efficient to prevent the biomagnification of any organic chemical. For chemicals with K OW values of <10 1, we found that biomagnification of persistent chemicals was constrained by the water–air partition ratio ( K WA ) rather than K OA . Differences in physiology may need to be considered in bioaccumulation assessments of air-breathing species.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.514

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.036
GPT teacher head0.308
Teacher spread0.272 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2023
Admission routes2
Has abstractyes

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