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Record W4385070924 · doi:10.1002/cjce.25050

Cyclic potentiodynamic passivation of <scp>316L</scp> stainless steels of different crystallographic orientation produced by laser powder bed fusion: Towards the improvement of corrosion resistance

2023· article· en· W4385070924 on OpenAlexafffundvenue
Rong Gu, Satria Robi Trisnanto, Mathieu Brochu, Sasha Omanovic

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2023
Typearticle
Languageen
FieldMaterials Science
TopicHydrogen embrittlement and corrosion behaviors in metals
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPassivationMaterials scienceCorrosionDielectric spectroscopyPitting corrosionAqueous solutionCrystalliteElectrochemistryCyclic voltammetryMetallurgyComposite materialElectrodeLayer (electronics)Chemistry

Abstract

fetched live from OpenAlex

Abstract The influence of cyclic potentiodynamic passivation (CPP) of 316L stainless steels (SS) of different crystallographic orientation produced by laser powder bed fusion (LPBF) on the resulting general and pitting corrosion resistance is discussed. CPP was performed by cyclic voltammetry in aqueous 0.1 M NaNO 3 . Electrochemical tests including open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and linear potentiodynamic polarization were employed to evaluate the resulting corrosion properties of the surfaces in aqueous 3.5 wt.% NaCl. It was found that the CPP method enables the formation of a passive oxide surface film which significantly improved the materials' general and pitting corrosion resistance in comparison to the naturally‐formed passive film under the experimental conditions investigated. It was also found that the general corrosion resistance, for both the unmodified (naturally‐passivated) and CPP‐modified LPBF 316L samples, decreased in the order of {111} > {100} > polycrystalline > {110}. Although the CPP‐modified samples showed a significantly lower current in the passive region and higher pitting potentials, in comparison to the unmodified samples, their crystalline structure was found not to have any influence on the corresponding behaviours.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.212
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2023
Admission routes3
Has abstractyes

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Same venueThe Canadian Journal of Chemical EngineeringSame topicHydrogen embrittlement and corrosion behaviors in metalsFrench-language works237,207