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Record W4385257524 · doi:10.1002/pen.26418

Effects of tire‐derived pyrolytic carbon black and pyrolytic heavy oil on the curing and mechanical properties of styrene‐butadiene rubber composites

2023· article· en· W4385257524 on OpenAlexaff
Sangit Paul, Manjur Rahaman, Suman Kumar Ghosh, Palash Das, Ankur Katheria, Trisita Ghosh, Narayan Chandra Das

Bibliographic record

VenuePolymer Engineering and Science · 2023
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposites and Properties
Canadian institutionsHeritage College
FundersScience and Engineering Research BoardIndian Institute of Technology KharagpurDepartment of Science and Technology, Ministry of Science and Technology, India
KeywordsMaterials scienceNatural rubberCarbon blackComposite materialStyrene-butadienePyrolytic carbonUltimate tensile strengthTear resistanceCuring (chemistry)Dynamic mechanical analysisPolymerPyrolysisStyreneChemical engineeringCopolymer

Abstract

fetched live from OpenAlex

Abstract To investigate the potential effect of the pyrolytic carbon black (CBp) and pyrolytic heavy oil (HO), we incorporated them into styrene‐butadiene rubber (SBR) as reinforcing filler and plasticizing agent, respectively. Since the industrial N330 CB's specific surface area and other specifications adhere to the CBp standard, it has been selected as a benchmark. To test HO's applicability, conventional (AO) was substituted with it. We experimented with the N330 and CBp in the 1/1 variant. We examined the impacts on the cure behavior, physical characteristics such as density and hardness, mechanical properties, abrasion resistance, dynamic mechanical performance, and thermal properties of the filled SBR composites. According to field emission (FESEM) and transmission electron microscopy (TEM) micrographs, the increased tensile and tear strength is due to N330 black's superior dispersion over CBp in the rubber matrix. Better dispersion in N330 type CB is also justified by lower tan δ max from the dynamic mechanical analysis (DMA) study. Utilizing HO changes the curing conditions since it comprises more sulfur, which accelerates the formation of sulfur–sulfur cross‐links. Increased tensile and tear strengths, as well as improved dispersion in the rubber matrix, have been seen with the combined use of N330 and CBp. Meanwhile, HO could function well in place of commercially available AOs. Highlights The impact of scrap tires on human health and the environment is explored. Recovered carbon black (CB) from waste tire mixed with styrene‐butadiene rubber in various ratios. Pyrolytic oil is also incorporated to check its reusability in tire formulation. Similar cure characteristics and mechanical strength were found in the composites. Replacement of the conventional CB is proposed with recovered black.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.065
Threshold uncertainty score0.458

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.192
Teacher spread0.181 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2023
Admission routes1
Has abstractyes

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