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Record W4385738340 · doi:10.21203/rs.3.rs-3160851/v1

Soil Remediation, Waste Valorization and Biofuels from Cement Kiln Dust Landfills

2023· preprint· en· W4385738340 on OpenAlexafffund
Frank Zeman, Maryam Ghazizade, Colton Ellis

Bibliographic record

VenueResearch Square · 2023
Typepreprint
Languageen
FieldAgricultural and Biological Sciences
TopicBioenergy crop production and management
Canadian institutionsSt. Lawrence CollegeRoyal Military College of Canada
FundersCanadian Defence Academy
KeywordsEnvironmental scienceWaste managementEnvironmental remediationBiomass (ecology)BiofuelCement kilnKilnBioenergyEnvironmental engineeringEngineeringAgronomyContamination

Abstract

fetched live from OpenAlex

Abstract Bioenergy is viewed as a potential solution to anthropogenic greenhouse gas emissions. A sustainable deployment will depend on targeting marginal lands, particularly brownfield and degraded lands. In contrast, industrial remediation is often uneconomical or even desirable, especially if degraded lands passively return to a nature like state. Cement kiln dust landfills, containing saline solids, are such degraded lands that can be remediated biologically. Phytoremediation uses plants to transport a pollutant from contaminated soil into standing biomass. After harvest, it can be processed to separate salt, biofuel and process water. Work showed that salt recovery was preferential for large liquid to solid ratios with little effect for longer durations and higher temperatures. Elevated temperatures require additional energy while co-leaching more biomass, thus reducing total biomass to the kiln. Repeated soaking of smaller volumes of room temperature water also led to effective recovery. A multi stage design was investigated to reduce water consumption. The three stage counter current soaking method produced similar recovery while consuming 25% less water. The product is biomass with sufficient energy density for use as a solid fuel in the cement kiln at a carbon price below $20/t CO2. Long term remediation of cement kiln dust stockpiles is feasible on the century time scale while producing biofuel for the cement plant. Each square kilometer planted can substitute 5% of a cement kiln’s fuel while returning the waste to the kiln. This represents an early opportunity for combined remediation, waste valorization and bioenergy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.098
GPT teacher head0.323
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes2
Has abstractyes

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