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Record W4385738981 · doi:10.3997/2214-4609.202320201

Monitoring the Remediation of Organic Contaminants by Colloidal Activated Carbon: a Spectral Induced Polarization Study

2023· article· en· W4385738981 on OpenAlexaff
Angelos Almpanis, Lee Slater, Christopher Power

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldEnvironmental Science
TopicGroundwater flow and contamination studies
Canadian institutionsWestern University
Fundersnot available
KeywordsAdsorptionActivated carbonGroundwaterCloggingFlushingChemistryInertEnvironmental remediationDissolved organic carbonChemical engineeringEnvironmental chemistryContaminationEnvironmental engineeringEnvironmental scienceGeologyOrganic chemistryEngineeringGeotechnical engineering

Abstract

fetched live from OpenAlex

Summary Colloidal activated carbon (CAC) filters are becoming a popular option to remediate groundwater contaminated by DNAPLs and a real-time monitoring approach is desirable to assess its effectiveness. In this study, the spectral induced polarization (SIP) technique is evaluated for its applicability as a monitoring tool for DNAPL adsorption within CAC-filters. The adsorption of low-concentration (50 mg/L) tetrachloroethylene (PCE) in a CAC-filter was examined using a set of dynamic column experiments combined with SIP monitoring. The initial flushing of CAC into inert porous media was tracked by SIP monitoring, with an increase in both real and imaginary components of the complex conductivity. The CAC was then flushed out of the column via groundwater, leaving behind only carbon particles that will later adsorb the PCE. The process of flushing the CAC by groundwater indicated a decrease in both the SIP real and imaginary conductivities, with the imaginary holding a small amount of polarizability, which is likely associated with the remaining carbon particles. Finally, dissolved phase PCE was injected through the column, with insignificant changes in the simultaneous SIP response. This study suggests that SIP can monitor CAC within porous media but is insensitive to the low concentrations of dissolved phase PCE.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.238
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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