MétaCan
Menu
Back to cohort
Record W4386244928 · doi:10.1080/15361055.2023.2235179

Deuterium Stream Management Leaving the LPCE Column in a CECE Process for Heavy Water Detritiation

2023· article· en· W4386244928 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueFusion Science & Technology · 2023
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsKinectrics (Canada)
Fundersnot available
KeywordsDeuteriumHeavy waterTritiumExothermic reactionColumn (typography)ElectrolysisWater columnHydrogenElectrolysis of waterChemistryNuclear engineeringMaterials scienceNuclear physicsPhysicsGeologyMechanical engineeringPhysical chemistryEngineeringOrganic chemistry

Abstract

fetched live from OpenAlex

In heavy water detritiation using the combined electrolysis and catalytic exchange (CECE) process, deuterium leaving the electrolyzer is fed to the bottom of the liquid-phase catalytic exchange column (LPCE) in which tritium exchanges between the tritiated deuterium gas (moving upward in the LPCE column) and D2O liquid (moving downward in the LPCE column). Once the deuterium gas leaves the LPCE column, typically a trickle bed recombiner (TBR) is used to convert the incoming deuterium gas into the heavy water.In this study a different approach is presented in which instead of using a TBR, an additional LPCE column is used. In the additional LPCE column, deuterium gas is scrubbed with demineralized light water. This process alternative has many advantages over using a TBR. First, the oxidation of isotopic hydrogen is highly exothermic and requires a separate water-cooling circuit to maintain the temperature within the TBR. Second, a TBR requires a relatively complex internal design to ensure proper distribution of the gas, otherwise catalyst burnup may occur. Using a LPCE column instead of a TBR eliminates these complications. This paper presents a high-level layout of the process plant in which a LPCE column is used instead of a TBR. Column modeling and results are also presented.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score0.247

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.280
Teacher spread0.261 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it