The Effect of Linker‐to‐Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene‐Based Rare‐Earth Metal–Organic Frameworks (Small 36/2023)
Bibliographic record
Abstract
Rare-Earth Metals Article number 2302173 by Ashlee J. Howarth and co-workers focuses on the design and synthesis of nine new isostructural rare-earth cluster-based metal-organic frameworks (MOFs). The rare-earth ions used are highlighted on the periodic table in the image. The MOF, named CU-10 (CU = Concordia University), is comprised of pyrene-based linkers that when excited with UV-light can be used to generate singlet oxygen. The image shows the pyrene-based linkers being excited with rays of UV-light. The singlet oxygen is used to selectively oxidize and detoxify a mustard gas simulant, 2-chloroethyl ethyl sulfide, and the reaction is performed in methanol. The work highlights how linker-to-metal energy transfer from the pyrene linker to different rare-earth metal ions effects the generation of singlet oxygen and subsequent oxidation reaction.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".