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Record W4386809616 · doi:10.1002/admt.202300811

Stimuli‐Responsive Optical Switching Patterns in Millimetric Hydrogel Frames: Nanomaterial‐Free Anti‐Counterfeiting Technology

2023· article· en· W4386809616 on OpenAlexafffund
Sinthuran Jegatheeswaran, Dae Kun Hwang

Bibliographic record

VenueAdvanced Materials Technologies · 2023
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence and Fluorescent Materials
Canadian institutionsToronto Metropolitan UniversitySt. Michael's Hospital
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsNanomaterialsNanotechnologyMaterials scienceMicroscale chemistryComputer science

Abstract

fetched live from OpenAlex

Stimuli‐responsive materials are employed in numerous on‐demand applications, such as anti‐counterfeiting. Although innovative hybrid spectral/graphical approaches have gained wide attention, they are limited by the need for user training and sophisticated technologies to decode the covert pattern which can be achieved through toxic organic dyes, pigments, up‐conversion crystals, nanoparticles, or self‐assembly of colloidal particles within a hydrogel framework. These approaches also involve a lengthy multistep fabrication that consumes several days. Although optical nanomaterials, which are responsive to external stimuli, such as magnetic field, can undergo a quicker self‐assembly, additional equipment is required to generate external fields and the use of nanomaterials alone limits this technology's wide applicability in consumer goods especially on food or pharmaceuticals. Herein, a nanomaterial‐free technology is demonstrated that utilizes various microscale motifs to display an optical shifting behavior without the need for passive or active assembly of colloidal particles, and any toxic dyes, pigments, or nanomaterials. The optical shifting property is purely induced by hydrogel porous microstructures and resulting light scattering. The slit channel lithography technique makes it easy for users to authenticate products using a simple smartphone device or inverted microscope by validating the optical switching behaviors of motifs embedded in hydrogel frames.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0020.002
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0020.002
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.272
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2023
Admission routes2
Has abstractyes

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