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Record W4386923990 · doi:10.1016/j.egyr.2023.09.058

Hydrogen production by steam reforming of fusel oil over nickel deposited on pyrolyzed rice husk supports

2023· article· en· W4386923990 on OpenAlexaff
Porapak Suriya, Natthawan Prasongthum, Paweesuda Natewong, Thanakorn Wasanapiarnpong, Xinhua Gao, Tiansheng Zhao, Jumei Tian, Sareena Mhadmhan, Tham Le Mai Hong, Prasert Reubroycharoen

Bibliographic record

VenueEnergy Reports · 2023
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsUniversity of Regina
FundersSchool of Aerospace Science and TechnologyChulalongkorn University
KeywordsHuskPyrolysisFusel alcoholSteam reformingMaterials scienceNickelCatalysisHydrogen productionPyrolysis oilHydrogenChemical engineeringChemistryNuclear chemistryMetallurgyOrganic chemistryAlcohol

Abstract

fetched live from OpenAlex

Fusel oil is mixed alcohol as a by-product of ethanol production, and it can be used as a cheap and renewable source to produce Hydrogen (H2) via steam reforming. Silicon carbide (SiC) was successfully synthesized by pyrolysis of rice husk at different temperatures (1300, 1500, and 1700 °C) and was used as a support for a nickel (Ni) catalyst in steam reforming of fusel oil. The results exhibited pyrolysis temperature had a significant effect on the structure and crystalline phase of SiC, where pyrolysis of rice husk over 1500 °C resulted in the formation of a rod structure and β-SiC phase. The surface area of pyrolyzed rice husk was obtained for 19, 64, and 25 m2/g at pyrolysis temperatures of 1300, 1500, and 1700 °C, respectively. The performance of the Ni on the pyrolyzed rice husk support on steam reforming of fusel oil (SRF) was investigated at 700 °C and compared with Ni on commercial SiC. The Ni/SiC1500 exhibited the highest catalytic performance, and its activity remained almost constant during a 300 min stability test. The H2 yield produced from the Ni/SiC1500 was 29% after 180 min and remained stable because the unique rod structure and β-SiC phase reduced carbon formation, thus giving an excellent performance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.017
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.225
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2023
Admission routes1
Has abstractyes

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