MétaCan
Menu
Back to cohort
Record W4386961800 · doi:10.1002/0471125474.tox158

Diacetyl

2023· other· en· W4386961800 on OpenAlexaff
Evan M. Beckett, Anders Abelmann, Marc A. Maier

Bibliographic record

VenuePatty's Toxicology · 2023
Typeother
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsStantec (Canada)
Fundersnot available
KeywordsDiacetylChemistryFood scienceOdorFood spoilagePopulationFlavorToxicologyOrganic chemistryMedicineBiologyBacteria

Abstract

fetched live from OpenAlex

Abstract Diacetyl is the simplest diketone. It occurs endogenously in humans, is a natural byproduct of bacterial fermentation and pyrolysis of organic matter, and is present naturally in a number of foods. In its pure form, diacetyl is a greenish‐yellow liquid that is moderately soluble in water and has a very strong buttery, quinone‐like, or chlorine‐like odor. It has been used as a synthetic food additive and flavoring, most notably in microwave popcorn, for its buttery and caramel or toffee notes; however, since the mid‐2000s, its use has declined in favor of substitutes. Diacetyl has also been used as a reactant or starting material in chemical and/or biochemical reactions. Exposure to the general population is ubiquitous, not just from use and consumption of flavored consumer products and foods, but also through naturally occurring diacetyl in various foodstuffs and beverages and direct or secondhand exposure to tobacco smoke. Diacetyl has low toxicity from ingestion and dermal exposure. Its respiratory toxicity potential has been thoroughly evaluated via animal studies. As with most volatile organic compounds, the most sensitive health endpoint is upper airways effects and inflammation. Findings from some epidemiological studies have suggested that, at very high concentrations, diacetyl may cause reduced lung function and even severe restrictive or obstructive lung diseases, including bronchiolitis obliterans. In addition, the weight of the evidence indicates that diacetyl is neither a teratogen, nor a carcinogen. Diacetyl's potential as a sensory irritant and respiratory sensitizer remains equivocal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.035
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.226
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2023
Admission routes1
Has abstractyes

Explore more

Same venuePatty's ToxicologySame topicAdvanced Chemical Sensor TechnologiesFrench-language works237,207