Morphogenesis of Biogenic Phenolic Mesocrystals Mediated by Competitive Intermolecular Interactions
Bibliographic record
Abstract
The size and shape of the mesocrystals directly determine their properties, making the associated morphogenesis a means to engineer advanced materials from biogenic molecules. Unfortunately, the promise of the latter has been scarcely demonstrated, given their inherent anisotropic covalent bonding and limited tendency to form ordered structures. Herein, we report a library of mesocrystals derived from 3,4,5-tri- O -galloylquinic acid, which is a naturally occurring polyphenol. The direct structural characterization uncovers the crystallization path as the initial densification of prenucleated nanoscale intermediates and the followed continuous ordering into the final morphological changes. We demonstrate the possibility of affording biogenic mesocrystals with tailorable colloidal behavior by gaining control of the competitive intermolecular interactions that direct the self-assembly process.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.006 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".