Redox-active ligands – a viable route to reactive main group metal compounds
Bibliographic record
Abstract
-amidophenolates, catecholates, dithiolenes, 1,2-benzendithiolates, 2-amidobenzenethiolates, reduced α-diimines, ferrocenyl and porphyrinates are capable of reversible oxidation and thus have the ability to act as sources of electrons for metal centres. These and other non-innocent ligands have been employed in coordination complexes of base transition metals to influence their redox chemistry and afford compounds with useful catalytic, optical, magnetic and conducting properties. Despite the focus in contemporary main group chemistry on designing reactive compounds with potential catalytic activity, comparatively few studies exploring the chemistry of main group metal complexes incorporating redox-active ligands have been reported. This article highlights relevant chemical reactivity and electrochemical studies that probe the oxidation/reduction of main group metal compounds possessing redox-active ligands and comments on the prospects for this relatively untapped avenue of research.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.003 | 0.002 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.014 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".