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Record W4389861867 · doi:10.1080/07370652.2023.2295281

Strategy for improving the energy output efficiency of TKX-50: introduction of nitroamine explosives

2023· article· en· W4389861867 on OpenAlexaff
Wang Shu-ji, Di Wang, Xiaole Sun, Yong Hu, Pengfei Zhu, Xueyong Guo

Bibliographic record

VenueJournal of Energetic Materials · 2023
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsMD Precision (Canada)
FundersNational Natural Science Foundation of China
KeywordsEnergetic materialExplosive materialMaterials scienceThermal decompositionCombustionDecompositionChemical engineeringThermodynamicsChemistryPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

TKX-50 has attracted the attention of many researchers because of its low sensitivity and high energy characteristics. However, the experimental results show that there is a big gap between the energy level of TKX-50 and the theoretical value. Introducing nitroamine explosives RDX or HMX to stimulate the energy release of TKX-50 is of great significance for improving the energy release efficiency of TKX-50 and expanding its application in the field of energetic materials. In this paper, the properties of different TKX-50/RDX and TKX-50/HMX samples were investigated by thermal analysis and ignition combustion experiments. The results show that RDX has a more obvious catalytic effect on TKX-50. Adding 50% RDX reduces the peak thermal decomposition temperature of TKX-50 from 241.7°C to 218.7°C. At the same time, the flame propagation, maximum combustion pressure, and the pressurization rate of different samples during combustion were analyzed, and the reaction mechanism between RDX (or HMX) with TKX-50 was obtained. Because of the different catalytic effects of RDX and HMX on TKX-50, a strategy was proposed to construct the core-shell structure of TKX-50 to improve the reaction characteristics and energy release efficiency of TKX-50.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.080
Threshold uncertainty score0.408

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.218
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2023
Admission routes1
Has abstractyes

Explore more

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