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Record W4390740514 · doi:10.1002/mrm.30002

First in‐human evaluation of [<scp>1‐<sup>13</sup>C</scp>]pyruvate in <scp>D<sub>2</sub>O</scp> for hyperpolarized <scp>MRI</scp> of the brain: A safety and feasibility study

2024· article· en· W4390740514 on OpenAlexaff
Kofi Deh, Guannan Zhang, Angela Hijin Park, Charles H. Cunningham, Nadia Bragagnolo, Serge K. Lyashchenko, Shake Ahmmed, Avigdor Leftin, Elizabeth Coffee, Hedvig Hricak, Vesselin Z. Miloushev, Marius E. Mayerhoefer, Kayvan R. Keshari

Bibliographic record

VenueMagnetic Resonance in Medicine · 2024
Typearticle
Languageen
FieldChemistry
TopicAdvanced NMR Techniques and Applications
Canadian institutionsUniversity of TorontoSunnybrook Health Science Centre
FundersNational Institute of Biomedical Imaging and BioengineeringNational Institutes of HealthNational Cancer InstituteThompson Family FoundationPeter Michael FoundationMemorial Sloan-Kettering Cancer Center
KeywordsIn vivoNuclear magnetic resonanceChemistryMetaboliteNuclear medicineAnalytical Chemistry (journal)MedicinePhysicsChromatographyBiochemistryBiology

Abstract

fetched live from OpenAlex

Abstract Purpose To investigate the safety and value of hyperpolarized (HP) MRI of [1‐ 13 C]pyruvate in healthy volunteers using deuterium oxide (D 2 O) as a solvent. Methods Healthy volunteers ( n = 5), were injected with HP [1‐ 13 C]pyruvate dissolved in D 2 O and imaged with a metabolite‐specific 3D dual‐echo dynamic EPI sequence at 3T at one site (Site 1). Volunteers were monitored following the procedure to assess safety. Image characteristics, including SNR, were compared to data acquired in a separate cohort using water as a solvent ( n = 5) at another site (Site 2). The apparent spin–lattice relaxation time (T 1 ) of [1‐ 13 C]pyruvate was determined both in vitro and in vivo from a mono‐exponential fit to the image intensity at each time point of our dynamic data. Results All volunteers completed the study safely and reported no adverse effects. The use of D 2 O increased the T 1 of [1‐ 13 C]pyruvate from 66.5 ± 1.6 s to 92.1 ± 5.1 s in vitro, which resulted in an increase in signal by a factor of 1.46 ± 0.03 at the time of injection (90 s after dissolution). The use of D 2 O also increased the apparent relaxation time of [1‐ 13 C]pyruvate by a factor of 1.4 ± 0.2 in vivo. After adjusting for inter‐site SNR differences, the use of D 2 O was shown to increase image SNR by a factor of 2.6 ± 0.2 in humans. Conclusions HP [1‐ 13 C]pyruvate in D 2 O is safe for human imaging and provides an increase in T 1 and SNR that may improve image quality.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.006
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.438
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.006
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.320
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2024
Admission routes1
Has abstractyes

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