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Behavior of strain stripe networks in barium titanate nanocrystals on crossing its ferroelectric phase transition

2024· article· en· W4391134737 on OpenAlexfundno aff
Jiecheng Diao, Longlong Wu, Ana F. Suzana, Emil S. Božin, Edoardo Zatterin, Steven Leake, Ross Harder, Wonsuk Cha, Milinda Abeykoon, Jiadong Fan, Huaidong Jiang, Ian Robinson

Bibliographic record

VenuePhysical Review Materials · 2024
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced X-ray Imaging Techniques
Canadian institutionsnot available
FundersBasic Energy SciencesBrookhaven National LaboratoryEngineering and Physical Sciences Research CouncilNational Natural Science Foundation of ChinaU.S. Department of EnergyOffice of ScienceMajor State Basic Research Development Program of ChinaEnvironmental Studies Research FundsNational Science Foundation
KeywordsTetragonal crystal systemBarium titanateMaterials scienceFerroelectricityCondensed matter physicsPhase transitionNanocrystalPhase (matter)Strain (injury)DiffractionPiezoelectricityDomain (mathematical analysis)CrystallographyOpticsCrystal structureNanotechnologyOptoelectronicsPhysicsDielectricComposite materialChemistryQuantum mechanics

Abstract

fetched live from OpenAlex

Nanoscale strain networks are reported in <a:math xmlns:a="http://www.w3.org/1998/Math/MathML"><a:mrow><a:mi>BaTi</a:mi><a:msub><a:mi mathvariant="normal">O</a:mi><a:mn>3</a:mn></a:msub></a:mrow></a:math> (BTO) crystals of 300 nm size using Bragg coherent diffractive imaging. BTO nanocrystals with clear facets were chosen to identify the crystallographic directions, allowing the strain field direction and periodicity to be studied in detail. Stripes of strain were observed, which were both stable and preserved in tetragonal and cubic phases at elevated temperatures, above the tetragonal-to-cubic phase transition. A finite element analysis approach was used to simulate the domain structures inside a BTO crystal and to understand the origins of the strain stripes as piezoelectric blocks. A <c:math xmlns:c="http://www.w3.org/1998/Math/MathML"><c:msup><c:mn>180</c:mn><c:mo>∘</c:mo></c:msup></c:math> domain model gives a better qualitative match to the experimental images. Published by the American Physical Society 2024

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.371
Teacher spread0.351 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2024
Admission routes1
Has abstractyes

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