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Record W4391640333 · doi:10.1021/acs.langmuir.3c03394

Ti-Doped AgNbO<sub>3</sub> as Novel Dense Diffusion Barriers of Limiting Current Oxygen Sensors

2024· article· en· W4391640333 on OpenAlexaff
Ke Shan, Davoud Dastan, Lili Zhang, Zhongzhou Yi, Fengrui Zhai, Yunlong He, Mengyang Huang, Azadeh Jafari, Mustafa K. A. Mohammed, Azadeh Farzaneh

Bibliographic record

VenueLangmuir · 2024
Typearticle
Languageen
FieldMaterials Science
TopicElectronic and Structural Properties of Oxides
Canadian institutionsSimon Fraser University
FundersNational Natural Science Foundation of China
KeywordsOxygen sensorLimiting currentElectrolyteOxygenDiffusionMaterials scienceDiffusion barrierAnalytical Chemistry (journal)DopingYttria-stabilized zirconiaPartial pressureHydrogenFabricationAtmospheric temperature rangeElectrochemistryNanotechnologyChemical engineeringChemistryOptoelectronicsElectrodeCubic zirconiaLayer (electronics)ThermodynamicsCeramicComposite materialPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

The oxygen sensors with limiting current derived from a dense diffusion barrier have an excellent advantage of detecting oxygen partial pressure by controlling the ratio of air and fuel in combustion environments. Therefore, AgNb 1– x Ti x O 3−δ (wherein x varies from 0.1 to 0.3) was prepared as such a dense diffusion barrier layer for sensor application. Among the investigated compositions as a new condensed barrier for the diffusion of sensors, AgNb 1– x Ti x O 3−δ ( x = 0.1, 0.2, 0.3) exhibits oxygen ionic conductivities from 1.37 × 10 –4 to 5.78 × 10 –3 S·cm –1 in the temperature range of 600–900 °C and outstanding stable electrochemical properties. Herein, we employ these novel materials as dense diffusion barriers and 8 mol % zirconia stabilized by yttria (8YSZ) as a solid-state electrolyte for the fabrication of the oxygen sensors with limiting current. We observed a direct connection between the limiting current and oxygen content within the interval of 0.5–5.0 mol % at 800 °C and a low working voltage. The increase of Ti-doping amount in AgNbO 3 accelerates the sensing response to oxygen gas and promotes the service life of the sensor.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.506

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.244
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes1
Has abstractyes

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