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Record W4392598302 · doi:10.5194/egusphere-egu24-3051

A novel high-resolution in situ tool for studying biogeochemical processes in aquatic systems: The Lake Aiguebelette case study

2024· preprint· en· W4392598302 on OpenAlexaff
Roberto Grilli, Tonya DelSontro, Josette Garnier, Frédérick Jacob, Julien Némery

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicAquatic Invertebrate Ecology and Behavior
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsBiogeochemical cycleIn situAquatic ecosystemEnvironmental scienceOceanographyComputer scienceGeologyEnvironmental chemistryGeographyChemistryMeteorology

Abstract

fetched live from OpenAlex

Inland waters are a significant source of atmospheric methane (CH4), a greenhouse gas (GHG) 34-85 times stronger than carbon dioxide (on 100 to 20-yr timescales) and responsible for ~23% of global radiative forcing. Of the GHGs produced by inland waters (i.e., carbon dioxide, CH4 and nitrous oxide), CH4 is responsible for ~75% of the climatic impact of aquatic GHG emissions with aquatic CH4 emissions comparable to the largest global CH4 emitters - wetlands and agriculture. Considering that aquatic systems contribute up to half of global CH4 emissions and that CH4 is predominantly formed in anoxic environments such as lake sediments, the source and quantification of ubiquitous surface CH4 observed in most aquatic systems are a question of global importance.In this work we present the first deployment of a novel membrane inlet laser spectrometer (MILS) instrument, composed of a mid-infrared spectrometer for simultaneous detection of CH4, C2H6 and d13CH4 coupled with a fast response (t90 < 30sec) membrane extraction system. During a 1-day field campaign, we performed a 2D mapping of dissolved CH4, C2H6 and d13CH4 of surface water of Lake Aiguebelette (France) highlighting the advantages of continuous high-resolution mapping of dissolved gases.The results showed the presence of CH4 sources less enriched in 13C in the littoral zone (presumably the littoral anoxic sediments). The CH4 pool became more enriched in 13C with distance from shore, suggesting that oxidation processes prevailed over epilimnetic CH4 production. The data obtained were in line with recent multi-lake studies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.026
Threshold uncertainty score0.051

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.001
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.035
GPT teacher head0.276
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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