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Record W4392759765 · doi:10.5194/egusphere-egu24-14460

Age of air from ACE-FTS measurements of sulfur hexafluoride

2024· preprint· en· W4392759765 on OpenAlexaff
Laura Saunders, Kaley A. Walker, G. P. Stiller, T. von Clarmann, Florian Haenel, Hella Garny, Eric Ray, David A. Plummer, Harald Bönisch, Andreas Engel, Johannes C. Laube, Patrick E. Sheese

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of WaterlooEnvironment and Climate Change CanadaUniversity of Toronto
Fundersnot available
KeywordsSulfur hexafluorideSulfurEnvironmental scienceChemistryMaterials scienceMetallurgyOrganic chemistry

Abstract

fetched live from OpenAlex

The Brewer-Dobson Circulation (BDC) is one of the main determinants of trace gas distributions in the atmosphere. Climate models predict that atmospheric warming will cause the BDC to accelerate, modifying where greenhouse gases are most active and impacting the radiative properties of the atmosphere, resulting in a feedback effect. This acceleration is difficult to verify with observations because the speed of the BDC cannot be measured directly. However, changes in stratospheric transport can be identified using the stratospheric age of air, defined as the time since an air parcel entered the stratosphere from the troposphere. A decrease in age of air at higher latitudes would suggest a reduction in transit times, signifying an acceleration of the BDC. Age of air can be calculated using long-lived “clock tracers” such as sulfur hexafluoride (SF6), an industrial gas that is produced in the troposphere, has a negligible seasonal cycle, and has no stratospheric sinks. Due to its small concentrations, measurements have been historically limited, but detecting changes in age of air derived from SF6 requires a long-term, and ideally consistent (i.e., measured by the same instrument), time series. The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) provides the longest available vertically-resolved record of SF6, spanning 2004 to the present. This study presents a new age of air product derived from the ACE-FTS SF6 dataset using an updated version of the method used for the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) SF6 dataset, which spans the 2002-2012 period. In this presentation, the method for age of air calculation will be presented along with comparisons with other age of air profile datasets derived from MIPAS and balloon measurements. The long-term trend in age of air will be estimated using this new product with the goal of corroborating the predictions made by climate models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.030

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.040
GPT teacher head0.245
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2024
Admission routes1
Has abstractyes

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