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Record W4392814001 · doi:10.26434/chemrxiv-2024-k0sgz

Microplastic particles contain ice nucleation sites that can be deactivated by atmospheric aging

2024· preprint· en· W4392814001 on OpenAlexafffund
Teresa M. Seifried, Sepehr Nikkho, Aurelio Morales Murillo, Lucas J. Andrew, Edward R. Grant, Allan K. Bertram

Bibliographic record

VenueChemRxiv · 2024
Typepreprint
Languageen
FieldEnvironmental Science
TopicMicroplastics and Plastic Pollution
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaAustrian Science FundCotton Incorporated
KeywordsIce nucleusMicroplasticsNucleationAtmospheric sciencesEnvironmental scienceEnvironmental chemistryMineralogyChemistryGeology

Abstract

fetched live from OpenAlex

Recent research has shown that microplastics are widespread in the atmosphere. However, we know little about their ability to nucleate ice and impact cloud glaciation. Ice nucleation by microplastics could also limit their long-range transport and global distributions. The present study explores the heterogeneous ice nucleation activity of seven microplastic samples in the immersion-freezing mode. Two polypropylene and one polyethylene terephthalate sample froze heterogeneously with median freezing temperatures of -20.9°C, -23.2°C and -21.9°C, respectively. The number of ice nucleation sites per surface area, n_s (T), ranged from 10-1 to 104 cm-2 in a temperature interval of -15 to -25°C, which is comparable to that of volcanic ash and fungal spores. After exposure to ozone or a combination of UV light and ozone, simulating atmospheric aging, the ice nucleation activity decreased in some cases and remained unchanged in others. An initial assessment using microplastic concentrations reported in the literature and our freezing data suggest that microplastics may influence cloud glaciation in some situations, but more studies are needed to confirm this initial assessment. Ice nucleation by microplastics may also impact their long-range transport and global distribution of microplastics based on a comparison of our freezing results and those of fungal spores.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.210
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2024
Admission routes2
Has abstractyes

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