Replication data for measurement report: Evolution and distribution of NH3 over Mexico City from ground-based and satellite infrared spectroscopic measurements
Bibliographic record
Abstract
This dataset of atmospheric ammonia (NH3) has been generated from solar absorption spectra measured in central Mexico using ground-based Fourier-Transform Infrared (FTIR) spectrometers. The FTIR experiments have been operated by the “Spectroscopy and Remote Sensing” Research Group of the ICAyCC-UNAM (Instituto de Ciencias de la Atmósfera y Cambio Climático of the Universidad Nacional Autónoma de México, http://www.epr.atmosfera.unam.mx/) Related Publication: Herrera, B., Bezanilla, A., Blumenstock, T., Dammers, E., Hase, F., Clarisse, L., Magaldi, A., Rivera, C., Stremme, W., Strong, K., Viatte, C., Van Damme, M., and Grutter, M.: Measurement report: Evolution and distribution of NH3 over Mexico City from ground-based and satellite infrared spectroscopic measurements, Atmos. Chem. Phys. https://doi.org/10.5194/acp-2022-217, Accepted, 2022. Abstract: Ammonia (NH3) is the most abundant alkaline compound in the atmosphere, with consequences for the environment, human health, and radiative forcing. In urban environments, it is known to play a key role in the formation of secondary aerosols through its reactions with nitric and sulphuric acids. However, there are only a few studies about NH3 in Mexico City. In this work, atmospheric NH3 was measured over Mexico City between 2012 and 2020 by means of ground-based solar absorption spectroscopy using Fourier transform infrared (FTIR) spectrometers at two sites (urban and remote). Total columns of NH3 were retrieved from the FTIR spectra and compared with data obtained from the Infrared Atmospheric Sounding Interferometer (IASI) satellite instrument. The diurnal variability of NH3 differs between the two FTIR stations and is strongly influenced by the urban sources. Most of the NH3 measured at the urban station is from local sources, while the NH3 observed at the remote site is most likely transported from the city and surrounding areas. The evolution of the boundary layer and the temperature play a significant role in the recorded seasonal and diurnal patterns of NH3. Although the vertical columns of NH3 are much larger at the urban station, the observed annual cycles are similar for both stations, with the largest values in the warm months, such as April and May. The IASI measurements underestimate the FTIR NH3 total columns by an average of 32.2 ± 27.5 % but exhibit similar temporal variability. The NH3 spatial distribution from IASI shows the largest columns in the northeast part of the city. In general, NH3 total columns over Mexico City exhibited an average annual increase of 92 ± 3.9 x 1013 molecules/cm2 yr (urban) and 8.4 ± 1.4 x 1013 molecules/cm2 yr (remote) was observed in Mexico City at both FTIR stations and a decadal increase of 62 % with IASI data. Description UNAM_FTIRdata.csv: Atmospheric composition measurements made at the Universidad Nacional Autónoma de Mexico Observatory on the rooftop of the Instituto de Ciencias de la Atmósfera y Cambio Climático (UNAM, 19.33°N, 99.18°W, 2280 m.a.s.l.) located at the south of Mexico City. These are retrieved from Fourier Transfor InfraRed (FTIR) solar absorption spectra recorded with a Vertex 80 spectrometer from April 2012 to October 2019. The dataset contains the local time (YYYY-MM-DD hh:mm:ss AM/PM), the total columns (molecules/cm2), total error (molecules/cm2), systematic error (molecules/cm2), random error (molecules/cm2), and Degrees of Freddom (DOF).
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.009 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.003 | 0.006 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.002 | 0.001 |
| Open science | 0.002 | 0.002 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.030 | 0.015 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".