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Record W4395114137 · doi:10.1016/j.jechem.2024.04.018

Sustainable ammonia synthesis: An in-depth review of non-thermal plasma technologies

2024· article· en· W4395114137 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Energy Chemistry · 2024
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsWestern University
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsPlasmaAmmoniaThermalNonthermal plasmaAmmonia productionMaterials scienceEnvironmental scienceChemistryPhysicsThermodynamicsBiochemistry

Abstract

fetched live from OpenAlex

Ammonia serves both as a widely used fertilizer and environmentally friendly energy source due to its high energy density, rich hydrogen content, and emissions-free combustion. Additionally, it offers convenient transportation and storage as a hydrogen carrier. The dominant method used for large-scale ammonia production is the Haber-Bosch process, which requires high temperatures and pressures and is energy-intensive. However, non-thermal plasma offers an eco-friendly alternative for ammonia synthesis, gaining significant attention. It enables ammonia production at lower temperatures and pressures using plasma technology. This review provides insights into the catalyst and reactor developments, which are pivotal for promoting ammonia efficiency and addressing existing challenges. At first, the reaction kinetics and mechanisms are introduced to gain a comprehensive understanding of the reaction pathways involved in plasma-assisted ammonia synthesis. Thereafter, the enhancement of ammonia synthesis efficiency is discussed by developing and optimizing plasma reactors and effective catalysts. The effect of other feeding sources, such as water and methane, instead of hydrogen is also presented. Finally, the challenges and possible solutions are outlined to facilitate energy-saving and enhance ammonia efficiency in the future.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.051
Threshold uncertainty score0.526

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.227
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it